---
_id: '12823'
abstract:
- lang: eng
  text: The energy crisis and dependence on fossil fuels forces societies to develop
    alternative pathways to secure energy supplies. Therefore, non‐fossil fuels such
    as biofuels and e‐fuels can help counteract the resulting demand for existing
    combustion engines. However, biofuels, like biodiesel, have disadvantages in terms
    of oxidation stability. In general, aging of biodiesel is a complex mechanism
    due to interaction of various components. In order to develop an ideal fuel, the
    mechanism must be understood in full detail. In this work, an attempt is made
    to simplify the system by using methyl oleate as a biodiesel model component.
    In addition, other fuel components of interest such as alcohols and their respective
    acids help to clarify the aging mechanism. This work used isopropylidene glycerol
    (solketal) as the main alcohol, 1‐octanol and octanoic acid. A holistic biodiesel
    aging scheme was developed by using generated data and evaluating the role of
    acids. They epoxidize unsaturated fatty acid via Prileschajev reactions. In addition,
    the role of epoxides in oligomerization reactions is confirmed. Moreover, the
    alcohols show that the suppression of oligomerization can be achieved by the reaction
    with methyl oleate. The alcohol‐dependent aging products were determined by quadrupole
    time‐of‐flight (Q‐TOF) mass spectrometry.
author:
- first_name: Julian
  full_name: Türck, Julian
  last_name: Türck
- first_name: Fabian
  full_name: Schmitt, Fabian
  last_name: Schmitt
- first_name: Lukas
  full_name: Anthofer, Lukas
  last_name: Anthofer
- first_name: Ralf
  full_name: Türck, Ralf
  last_name: Türck
- first_name: Wolfgang
  full_name: Ruck, Wolfgang
  last_name: Ruck
- first_name: Jürgen
  full_name: Krahl, Jürgen
  id: '68870'
  last_name: Krahl
citation:
  ama: 'Türck J, Schmitt F, Anthofer L, Türck R, Ruck W, Krahl J. Extension of Biodiesel
    Aging Mechanism–the Role and Influence of Methyl Oleate and the Contribution of
    Alcohols Through the Use of Solketal. <i>  ChemSusChem : chemistry &#38; sustainability,
    energy &#38; materials</i>. 2023;16(17). doi:<a href="https://doi.org/10.1002/cssc.202300263">10.1002/cssc.202300263</a>'
  apa: 'Türck, J., Schmitt, F., Anthofer, L., Türck, R., Ruck, W., &#38; Krahl, J.
    (2023). Extension of Biodiesel Aging Mechanism–the Role and Influence of Methyl
    Oleate and the Contribution of Alcohols Through the Use of Solketal. <i>  ChemSusChem :
    Chemistry &#38; Sustainability, Energy &#38; Materials</i>, <i>16</i>(17). <a
    href="https://doi.org/10.1002/cssc.202300263">https://doi.org/10.1002/cssc.202300263</a>'
  bjps: '<b>Türck J <i>et al.</i></b> (2023) Extension of Biodiesel Aging Mechanism–the
    Role and Influence of Methyl Oleate and the Contribution of Alcohols Through the
    Use of Solketal. <i>  ChemSusChem : chemistry &#38; sustainability, energy &#38;
    materials</i> <b>16</b>.'
  chicago: 'Türck, Julian, Fabian Schmitt, Lukas Anthofer, Ralf Türck, Wolfgang Ruck,
    and Jürgen Krahl. “Extension of Biodiesel Aging Mechanism–the Role and Influence
    of Methyl Oleate and the Contribution of Alcohols Through the Use of Solketal.”
    <i>  ChemSusChem : Chemistry &#38; Sustainability, Energy &#38; Materials</i>
    16, no. 17 (2023). <a href="https://doi.org/10.1002/cssc.202300263">https://doi.org/10.1002/cssc.202300263</a>.'
  chicago-de: 'Türck, Julian, Fabian Schmitt, Lukas Anthofer, Ralf Türck, Wolfgang
    Ruck und Jürgen Krahl. 2023. Extension of Biodiesel Aging Mechanism–the Role and
    Influence of Methyl Oleate and the Contribution of Alcohols Through the Use of
    Solketal. <i>  ChemSusChem : chemistry &#38; sustainability, energy &#38; materials</i>
    16, Nr. 17. doi:<a href="https://doi.org/10.1002/cssc.202300263">10.1002/cssc.202300263</a>,
    .'
  din1505-2-1: '<span style="font-variant:small-caps;">Türck, Julian</span> ; <span
    style="font-variant:small-caps;">Schmitt, Fabian</span> ; <span style="font-variant:small-caps;">Anthofer,
    Lukas</span> ; <span style="font-variant:small-caps;">Türck, Ralf</span> ; <span
    style="font-variant:small-caps;">Ruck, Wolfgang</span> ; <span style="font-variant:small-caps;">Krahl,
    Jürgen</span>: Extension of Biodiesel Aging Mechanism–the Role and Influence of
    Methyl Oleate and the Contribution of Alcohols Through the Use of Solketal. In:
    <i>  ChemSusChem : chemistry &#38; sustainability, energy &#38; materials</i>
    Bd. 16. Weinheim, Wiley (2023), Nr. 17'
  havard: 'J. Türck, F. Schmitt, L. Anthofer, R. Türck, W. Ruck, J. Krahl, Extension
    of Biodiesel Aging Mechanism–the Role and Influence of Methyl Oleate and the Contribution
    of Alcohols Through the Use of Solketal,   ChemSusChem : Chemistry &#38; Sustainability,
    Energy &#38; Materials. 16 (2023).'
  ieee: 'J. Türck, F. Schmitt, L. Anthofer, R. Türck, W. Ruck, and J. Krahl, “Extension
    of Biodiesel Aging Mechanism–the Role and Influence of Methyl Oleate and the Contribution
    of Alcohols Through the Use of Solketal,” <i>  ChemSusChem : chemistry &#38; sustainability,
    energy &#38; materials</i>, vol. 16, no. 17, 2023, doi: <a href="https://doi.org/10.1002/cssc.202300263">10.1002/cssc.202300263</a>.'
  mla: 'Türck, Julian, et al. “Extension of Biodiesel Aging Mechanism–the Role and
    Influence of Methyl Oleate and the Contribution of Alcohols Through the Use of
    Solketal.” <i>  ChemSusChem : Chemistry &#38; Sustainability, Energy &#38; Materials</i>,
    vol. 16, no. 17, 2023, <a href="https://doi.org/10.1002/cssc.202300263">https://doi.org/10.1002/cssc.202300263</a>.'
  short: 'J. Türck, F. Schmitt, L. Anthofer, R. Türck, W. Ruck, J. Krahl,   ChemSusChem :
    Chemistry &#38; Sustainability, Energy &#38; Materials 16 (2023).'
  ufg: '<b>Türck, Julian u. a.</b>: Extension of Biodiesel Aging Mechanism–the Role
    and Influence of Methyl Oleate and the Contribution of Alcohols Through the Use
    of Solketal, in: <i>  ChemSusChem : chemistry &#38; sustainability, energy &#38;
    materials</i> 16 (2023), H. 17.'
  van: 'Türck J, Schmitt F, Anthofer L, Türck R, Ruck W, Krahl J. Extension of Biodiesel
    Aging Mechanism–the Role and Influence of Methyl Oleate and the Contribution of
    Alcohols Through the Use of Solketal.   ChemSusChem : chemistry &#38; sustainability,
    energy &#38; materials. 2023;16(17).'
date_created: 2025-04-22T13:38:51Z
date_updated: 2025-06-26T07:47:02Z
department:
- _id: DEP1408
doi: 10.1002/cssc.202300263
external_id:
  isi:
  - '001025502300001'
  pmid:
  - '37220243'
intvolume: '        16'
isi: '1'
issue: '17'
keyword:
- biodiesel aging
- epoxide-dependent oligomerization
- solketal
- Prileschajew reaction
language:
- iso: eng
place: Weinheim
pmid: '1'
publication: '  ChemSusChem : chemistry & sustainability, energy & materials'
publication_identifier:
  eissn:
  - 1864-564X
  issn:
  - 1864-5631
publication_status: published
publisher: Wiley
status: public
title: Extension of Biodiesel Aging Mechanism–the Role and Influence of Methyl Oleate
  and the Contribution of Alcohols Through the Use of Solketal
type: scientific_journal_article
user_id: '83781'
volume: 16
year: '2023'
...