---
_id: '12836'
abstract:
- lang: eng
text: The complexity of biodiesel aging has shown that the mechanism needs further
research. The rate of aging product formation and associated interactions can
help improve fuel quality. Since biodiesel is a multicomponent system and constant
changes occur in the chemical environment, which interactions yield which products
must be shown in more detail. Particularly under observation was the correlation
between peroxides and epoxides. In addition, it is critical that the influence
and interactions of new drop-in fuel candidates be investigated. In this work,
the kinetics of the formation of aging products of methyl oleate (C18:1) are studied.
The aim was to reduce the complexity in order to be able to make more precise
and detailed statements about the mechanism. Ketones, acids, peroxide, and epoxide
values were recorded. A distinction is made between pure methyl oleate and mixtures
with 3 wt% isopropylidene glycerine (solketal). After solketal decomposed in the
blends, the aging process showed changes. The influence of solketal resulted in
a higher number of acids and epoxides over time. It implied that peroxides are
not necessarily the precursor of epoxides. In summary, correlation and solketal’s
influence showed that a sequence of aging products could be detected.
article_number: '3253'
author:
- first_name: Julian
full_name: Türck, Julian
last_name: Türck
- first_name: Fabian
full_name: Schmitt, Fabian
last_name: Schmitt
- first_name: Lukas
full_name: Anthofer, Lukas
last_name: Anthofer
- first_name: Anne
full_name: Lichtinger, Anne
last_name: Lichtinger
- first_name: Ralf
full_name: Türck, Ralf
last_name: Türck
- first_name: Wolfgang
full_name: Ruck, Wolfgang
last_name: Ruck
- first_name: Jürgen
full_name: Krahl, Jürgen
id: '68870'
last_name: Krahl
citation:
ama: 'Türck J, Schmitt F, Anthofer L, et al. Oxidation Kinetics of Neat Methyl Oleate
and as a Blend with Solketal. Energies : open-access journal of related scientific
research, technology development and studies in policy and management. 2023;16(7).
doi:10.3390/en16073253'
apa: 'Türck, J., Schmitt, F., Anthofer, L., Lichtinger, A., Türck, R., Ruck, W.,
& Krahl, J. (2023). Oxidation Kinetics of Neat Methyl Oleate and as a Blend
with Solketal. Energies : Open-Access Journal of Related Scientific Research,
Technology Development and Studies in Policy and Management, 16(7),
Article 3253. https://doi.org/10.3390/en16073253'
bjps: 'Türck J et al. (2023) Oxidation Kinetics of Neat Methyl Oleate
and as a Blend with Solketal. Energies : open-access journal of related scientific
research, technology development and studies in policy and management 16.'
chicago: 'Türck, Julian, Fabian Schmitt, Lukas Anthofer, Anne Lichtinger, Ralf Türck,
Wolfgang Ruck, and Jürgen Krahl. “Oxidation Kinetics of Neat Methyl Oleate and
as a Blend with Solketal.” Energies : Open-Access Journal of Related Scientific
Research, Technology Development and Studies in Policy and Management 16,
no. 7 (2023). https://doi.org/10.3390/en16073253.'
chicago-de: 'Türck, Julian, Fabian Schmitt, Lukas Anthofer, Anne Lichtinger, Ralf
Türck, Wolfgang Ruck und Jürgen Krahl. 2023. Oxidation Kinetics of Neat Methyl
Oleate and as a Blend with Solketal. Energies : open-access journal of related
scientific research, technology development and studies in policy and management
16, Nr. 7. doi:10.3390/en16073253,
.'
din1505-2-1: 'Türck, Julian ; Schmitt, Fabian ; Anthofer,
Lukas ; Lichtinger, Anne
; Türck, Ralf ; Ruck,
Wolfgang ; Krahl, Jürgen:
Oxidation Kinetics of Neat Methyl Oleate and as a Blend with Solketal. In: Energies :
open-access journal of related scientific research, technology development and
studies in policy and management Bd. 16. Basel, MDPI AG (2023), Nr. 7'
havard: 'J. Türck, F. Schmitt, L. Anthofer, A. Lichtinger, R. Türck, W. Ruck, J.
Krahl, Oxidation Kinetics of Neat Methyl Oleate and as a Blend with Solketal,
Energies : Open-Access Journal of Related Scientific Research, Technology Development
and Studies in Policy and Management. 16 (2023).'
ieee: 'J. Türck et al., “Oxidation Kinetics of Neat Methyl Oleate and as
a Blend with Solketal,” Energies : open-access journal of related scientific
research, technology development and studies in policy and management, vol.
16, no. 7, Art. no. 3253, 2023, doi: 10.3390/en16073253.'
mla: 'Türck, Julian, et al. “Oxidation Kinetics of Neat Methyl Oleate and as a Blend
with Solketal.” Energies : Open-Access Journal of Related Scientific Research,
Technology Development and Studies in Policy and Management, vol. 16, no.
7, 3253, 2023, https://doi.org/10.3390/en16073253.'
short: 'J. Türck, F. Schmitt, L. Anthofer, A. Lichtinger, R. Türck, W. Ruck, J.
Krahl, Energies : Open-Access Journal of Related Scientific Research, Technology
Development and Studies in Policy and Management 16 (2023).'
ufg: 'Türck, Julian u. a.: Oxidation Kinetics of Neat Methyl Oleate and as
a Blend with Solketal, in: Energies : open-access journal of related scientific
research, technology development and studies in policy and management 16 (2023),
H. 7.'
van: 'Türck J, Schmitt F, Anthofer L, Lichtinger A, Türck R, Ruck W, et al. Oxidation
Kinetics of Neat Methyl Oleate and as a Blend with Solketal. Energies : open-access
journal of related scientific research, technology development and studies in
policy and management. 2023;16(7).'
date_created: 2025-04-23T08:48:40Z
date_updated: 2025-06-25T13:13:39Z
department:
- _id: DEP1408
doi: 10.3390/en16073253
external_id:
isi:
- '000969447200001'
intvolume: ' 16'
isi: '1'
issue: '7'
keyword:
- oxidation kinetics
- biodiesel aging
- methyl oleate
- solketal
- alcohol influence
- sequence of aging products
language:
- iso: eng
place: Basel
publication: 'Energies : open-access journal of related scientific research, technology
development and studies in policy and management'
publication_identifier:
eissn:
- 1996-1073
publication_status: published
publisher: MDPI AG
status: public
title: Oxidation Kinetics of Neat Methyl Oleate and as a Blend with Solketal
type: scientific_journal_article
user_id: '83781'
volume: 16
year: '2023'
...